CATALOGUE OF SUBSTITUTIONS


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Number of examples: 311
Pulvermaling til industrivaskemaskiner - fra epoxy/polyester binder til polyester
Jensen Danmark skiftede fra en epoxy/polyester baseret pulvermaling (MAL kode 00-5) til en polyesterbaseret pulvermaling Mal kode 00-1. Malingen anvendes på det samme anlæg, har bedre tekniske egenskaber end den gamle og affaldet kan afleveres som erhvervsaffald. Der er en energimæssig besparelse (lavere temperatur). Til gengæld er den nyere maling dyrere i indkøb.
Jensen Denmark A/S - Friday, April 15, 2011



Traditionel beton substitueret med Grøn Beton og konstruktion uden brug af asfalt
I nærværende substitution, substitueres traditionel beton og gængse konstruktionsmetoder med anvendelsen af Grøn Beton og en konstruktionsløsninger uden brugen af asfalt, fugtisoleringsprodukter og reduceret CO2 udledning. Substitutionen er udført som et broprojekt under Center for Grøn Beton. Broen står sydvest for Tørring ved Vejle.
Alectia A/S - Wednesday, January 07, 2009



Vandtætningsprodukter til injicering uden miljø- og sundhedsskadelige stoffer
Substitution afvandtætningsprodukter indeholdende Diisobutylphthalat og Alkyldimethylamin med produkt uden disse 2 indholdsstoffer.
Alectia A/S - Wednesday, January 07, 2009



Substitution af problematiske klæbemidler ved fastgørelse af fugebånd i støbeskel
Substitution af anvendelse af klæbemiddel med miljø og arbejdsmiljøskadelige indholdsstoffer.

Til vedhæftning af fugebånd i støbeskel anbefales ofte brug af klæbemidler med indhold af miljø og arbejdsmiljøskadelige indholdsstoffer. Disse klæbemidler kan ofte undgås ved mekanisk vedhæftning til betonoverflader.
CG Jensen A/S - Wednesday, January 07, 2009



Organiske opløsningsmidler ved overfladebehandling af veje, cykelstier og P-pladser
Substitution af de blødgørende organiske opløsningsmidler der anvendes i Cutback-bitumen med emulsioner af vand og bitumen eller med rapsolie.
DOB I/S Dansk Overfladebehandling - Wednesday, January 07, 2009



Tætning af forskalningsforme uden PU-skum
Tidligere anvendtes polyurethanskum til tætning af forskallingsforme. PU-skummet er erstattet af alternative metoder.
Alectia People - Tuesday, September 30, 2008



Hulrumsisolering med papirgranulat
Til efterisolering af etageadskillelse mellem loft og øverste etage og bag brystninger, hvor der traditionelt benyttes mineraluldsgranulat.
Alectia People - Tuesday, September 30, 2008



Isolering med hør-formstykker
Bygningsisolering med hør-formstykker af skunk og skråvægge, hanebåndsloft, i vinduesbrystninger og i dæk over kælder mellem bjælker,hvor der traditionelt bliver benyttet mineralulds-formstykker.

Alectia People - Tuesday, September 23, 2008



Tætning af fuger i etageadskillelser
Ved tætning af etageadskillelser og lejlighedsadskillelser er PU-skum erstattet med skum uden polyurethan / isocyanat.
Enemærke & Petersen a/s - Tuesday, September 23, 2008



Vandtætning af fundamenter
NCC - Friday, July 04, 2008



Intermediate cleaning by recirculation-air blow system
Car cylinder heads made of alu-aloys are cleaned intermediately from cooling lubricants and chips in an inline recirculation-air blow-system without any agent.
Cooperation Centre Hamburg - Thursday, June 26, 2008



Cleaning of worm wheels by vibration before fitting
Cleaning of worm wheels made of brass from cutting oils and chips by vibration apparatus integrated in production line.
Cooperation Centre Hamburg - Thursday, June 26, 2008



Laser cleaning of waffle irons
Waffle irons in a baking line made of steel are cleaned during baking operation from baking residue automatically by a solid-state laser; thereafter continued baking process

Cooperation Centre Hamburg - Thursday, June 26, 2008



Laser cleaning of brake linings before powder coating
Brake pads made of steel are cleaned from oxides and minute organic residue automatically in the production line by a solid-state laser.
Cooperation Centre Hamburg - Thursday, June 26, 2008



Bio-cleaning for construction parts
Steel parts e.g. for construction are cleaned from oils, dust, corrosion protec., rust, welding residue and metal fines by a biological cleaning process in a multiple immersion plant (integrated pickling, fluxing and galvanising).
Cooperation Centre Hamburg - Thursday, June 26, 2008



Bio wash stand for small items
Small items from maintenance/repair made (e.g. cylinder heads) of steel, cast iron, alu, brass are cleaned from oils, greases and fines on a wash stand using a bio cleaner.
Cooperation Centre Hamburg - Thursday, June 26, 2008



Jet engine parts microphase cleaning to allow cracks detection
Jet engine parts from repair and maintenance made of stainless steel, nickel-alloys and titan are cleaned from grease, oil and combustion residue by a micro phase system in a one-chamber spray plant; thereafter crack detection.
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Cleaning of cast cylinder heads by shockwave technology
Cleaning after casting of cylinder heads made of aluminium from cast sand, smoothener and chips by shockwave technology; thereafter shipping for mechanical treatment.

Cooperation Centre Hamburg - Wednesday, June 25, 2008



Cleaning of resistance welding robots with CO2 pellets
Robots for resistance welding of car body parts are cleaned from slag and spatters by mobile blast machines and CO2 dry ice pellets. Thereafter normal welding operation of robots.
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Cleaning reels from die cutting by high pressure water jet
Reels from die cutting (eg for manufacturing plugs with many pins)made of stainless steel, copper alloys or tinned copper are cleaned from punching oils and tin flitter in a high-pressure water-jet (integrated in production line) using only tap water; thereafter application of plastic or welding.

Cooperation Centre Hamburg - Wednesday, June 25, 2008



Cleaning of motorbike repair parts with esters at a wash stand
Cleaning of motorbike repair parts at a washstand with vegetable oil based esters from dust, mineral oil, grease, soot, tar, metal fines, oxides, sand and salt. Thereafter repair and assembling.
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Lift rails cleaning with esters
Manual cleaning of rails for lifts made of steel from corrosionprotection (tectyl), oils, grease, dust, sand and rust using esters wiping with cotton rags; thereafter rails are fitted
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Blasting of ship's hull with CO2 ice pellets
Newly built ships made of steel covered with primer are cleaned of residue, oxides and soot from welding and gas cutting using CO2 pellets and a manual blasting equipment (pressed air operated), thereafter another corrosion protection paint is applied.
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Shipyard - Cleaning of small parts from repair with esters.
Small items from repair work and maintenance in a ship yard e.g. bearings, casings, bolts and sheets made of steel are cleaned from lubricants, oils, metal fines and sand by fatty acids esters on a wash stand.
Cooperation Centre Hamburg - Wednesday, June 25, 2008



Cables without lead, PVC and phthalates.
nkt-cables has developed cable installation without lead, PVC and phtalates. The new cable type NOPOVIC® is based on a mixture of halogenfree polymers such as PE, PP and EVA copolymers with added non-flamable minerals like magnesium and aluminium hydrates.

NKT-cables a/s - Tuesday, June 17, 2008



Substitution of phthalates with Castor oil
As a substitute for phthalates Danisco has developed a product based on Castor oil and acetic acid. The use of the product is primarely as a plasticizer for plastic used in food wrappings, children´s toys and medical equipment.
Danisco A/S - Tuesday, June 17, 2008



Alternatives to herbicides in apple orchards
Cover materials or cover crops can be an alterative to herbicides, without affecting fruit yield and quality. Earthworms thrives under rape straw but not under black polypropylene or by mechanical weeding. A questionaire showed that consumers are ready to pay more for apples produced witout herbicides.Mouse is a major problem where cover materials are used.


Environmental Protection Agency - Thursday, June 12, 2008



Deca-BDE and Alternatives in Electrical and Electronic Equipment
The study summarises information on the use of the brominated flame retardant Deca-BDE CAS No 1163-19-5 in electrical and electronic equipment (EEE) and describes suitable alternatives to Deca-BDE. The study has not identified any application of Deca-BDE in EEE for which substitution is not possible, from the scientific or technical point of view.
Environmental Protection Agency - Thursday, June 12, 2008



Afrensning af havemøbler - test
Specialmidler til at rense havemøbler af træ kan indeholde miljøbelastende stoffer, viser denne test fra IMS.
Informationscenter for Miljø & Sundhed - Tuesday, June 10, 2008



Indendørs fugemasser uden ftalater
9 hvide indendørs akrylfugemasser er testet af Informationscenter for Miljø og Sundhed. Otte af de ni indeholdt ftalater. Informationscenteret anbefaler 2 gode valg af fugemasser.
Informationscenter for Miljø & Sundhed - Tuesday, June 10, 2008



Brake cleaning
Lorry and van drum brakes are cleaned for repair- and maintenance purposes from mud, dust and sand by a hot water washer. This is a kind of wash stand fitted with a flow heater and a spray gun. The tap water is heated to 95°C and sprayed on the brakes thereby removing the dirt and also heating the brakes so they dry rapidly after cleaning. Thereafter the parts are reassembled.
Usually in garages aerosol cans containing highly volatile organic solvents are applied, having a high risk of fires and explosions as well as leading to inhalation of the solvents by the workers.
The German accident insurance recommends the hot water washers. The jet does not cause scaldings on the skin, because it is a very finely sprayed mist. When asked in Nov. 2007 the company confirmed, that they are still content with the process and that it is still being applied.
Cooperation Centre Hamburg - Wednesday, May 28, 2008



Disinfectants of endoskopes in machines
Products based on glutaraldehyde are used to sterilize flexible Endoscopes in machines. In certain cases other products can be used.


Alectia - Wednesday, May 28, 2008



Afrensning af trykdug ved offset på polypropylen
Til afrensning af trykdug for UV-trykfarver blev der tidligere anvendt Rensevæske nr. 144 fra Randers Kemiske Industri. Produktet inderholder bl.a. ethylacetat (cas 141-78-6 Ethyl acetate Ethylacetat ) og isopropanol, og har MAL-kode 4-1 (1993) og er mærket lokalirriterende (Xi)
Til opgaven anvendes nu et produkt, der indeholder ethanol og isopropanol. Dette produkt har MAL-kode(1993)2-1.
Superfos - Thursday, May 22, 2008



Rengøring af farvevalser fra UV-offset
Til afrensning af farvevalser fra UV-offset tryk er man gået fra et lokalirriterende produkt indeholdende ethylacetat (cas 141-78-6 Ethyl acetate ) med MAL-kodenummer 4-1 til et produkt indeholdende ethanolforbindelser med Mal-kodenummer 2-1.
Superfos - Wednesday, May 21, 2008



Afrensning af farvebakker i rensebar
Til vask af farvekasser fra offsettryk har virksomheden udskiftet et produkt med ethylacetat med et produkt med meget mindre fordamping. Det nye produkt er hudirriterende.
Superfos - Wednesday, May 21, 2008



Offset tryk på polypropylen - UV-farver
På virksomheden anvendes nu UV-farver til offset trykning på polypropylen emballage. Førhen anvendtes opløsningsmiddelbaserede farver.
Superfos - Wednesday, May 21, 2008



Snekkerens ved sprøjtestøbning i polypropylen
Ved sprøjtestøbning i polypropylen renses maskinen mellem farveskift. Tidligere anvendtes et faremærket produkt. Der anvendes nu et produkt, der ikke er faremærket - en harpiks på styrolbasis.
Superfos - Wednesday, May 21, 2008



Snekkerens ved sprøjtestøbning i polypropylen
Ved sprøjtestøbning i polypropylen renses maskinen mellem farveskift. Tidligere anvendtes tidligere et faremærket produkt. Der anvendes nu et produkt, der ikke er faremærket - en harpiks på styrolbasis.
Superfos - Wednesday, May 21, 2008



Alternativer til bly i erhvervsfiskeri
Alternativer til bly i erhvervsfiskeri er afprøvet. For synk lykkedes det at fremstille og afprøve alternativer af zink og støbejern. For synkeliner og vodtove lykkedes det ikke at fremstille et produktionsklare alternativer. Tøndeformede synk af zink og støbejern fungerer lige så fint som synk lavet af bly.
Miljøstyrelsen - Wednesday, April 23, 2008



Alternatives to chlorine in public svimming pools
Alternatives to desinfection of public svimming pools with chlorine is assessed in a project conducted for the Danish Environmental Protection Agency.
Miljøstyrelsen - Tuesday, April 22, 2008



Brug af rapsolie som køle-/smøremiddel.
Til doseringssmurte saveanlæg anvendes traditionelle køle-/smøremidler. Det er muligt at erstatte disse midler med almindelig rapsolie.
Aalborg aluminium Industri - Friday, March 28, 2008



Vandbaserede affedtningsmidler til metalemner
Når metalemner skal affedtes anvendes affedtningsmidler, der ofte indeholder sundhedsskadelige indholdsstoffer. Disse kan erstattes af vandbaserede produkter.
Alectia A/S - Thursday, March 27, 2008



Nødder erstatter vaskepulver i vaskemaskine
Det er muligt at anvende nødder til at vaske tøj i vaskemaskine i stedet for vaskepulver.
Alectia A/S - Thursday, March 27, 2008



Brug af robot til rengøring af dieselmotorer
Manuel rengøring af dieselmotorer i tog kan automatiseres ved brug af en robot.
Alectia A/S - Wednesday, March 26, 2008



Giftfri smøremidler i fødevareindustrien
For at sikre fødevarer den rette kvalitet er fødevareindustrien i Danmark meget opmærksomme på at undgå steder i produktionen, hvor levnedsmidler kan kontamineres af fx smøremidler, der kan dryppe ned i fødevarene. Branchen kræver fødevaregodkendte smøremidler. Det er muligt at få smøremidler, der ikke indeholder sundhedsskadelige indholdsstoffer.
Alectia A/S - Wednesday, March 26, 2008



Enzymer i bundmaling til lystbåde
Gængse bundmalinger til lystbåde indeholder ofte kobber og andre tungmetaller. Industrielle enzymer kan erstatte metallerne.
Alectia A/S - Friday, March 14, 2008



Brug af robot reducere forbruget af gift ved ukrudtsbekæmpelse.
Til bekæmpelse af ukrudt i frilandsgartnerier anvendes giftstoffer i større mængder. Udviklingen af en robot til ukrudtsbekæmpelse har reduceret brugen af giftstoffer til 1/1000 del af det normale.
Alectia A/S - Thursday, March 13, 2008



Brug af Chromit i stedet for Chrom 6 og Chrom 3 som korrosionsbeskyttelse
Ved el-galvanisering af emner i metal har der gennem mange år været anvendt Chrom 6 og Chrom 3, som korrosionsbeskyttelse. Det er muligt, at bruge Chromit i stedet for.


Alectia A/S - Thursday, March 13, 2008



Substitution af klor-/fluor-karbonater med sæbevand
Overfladerensning og vedligeholde af finelektroniske komponenter med klor-/flour holdige karbonater kan erstattes af en kombination af rensning med sæbevand, vandskyende væske og lufttørring.
Alectia A/S - Thursday, March 13, 2008



Disinfection of flexible Endoscopes
Disinfectants based on glutaraldehyde are used to sterilize flexible Endo-scopes. In certain cases products based on Peracetic acid can be used.
Alectia - Friday, March 07, 2008



Use of developer containing hydroquinon
At the Department of Radiology the developer Periomat Intra is used as a dental film developer. The developer contains hydroquinon which is carcinogenic. Instead Optimal developer can be used which is based on vitamin C
Alectia A/S - Monday, March 10, 2008



Ready-made ethidium bromide solutions
Ethidium bromide solution can be bought ready-made instead of producing it in the laboratories thus eliminating contact with the concentrated chemical
Alectia A/S - Monday, March 10, 2008



Production of acrylamide gels
Acrylamide gels are produced by use of acrylamide (acrylic amide) which is very poisonous. Instead it is possible to buy ready-made Acrylamide gels.
Alectia A/S - Monday, March 10, 2008



Use of hospital spirit to clean ear thermometers instead of isopropanol
The supplier of ear thermometers demands that they are cleaned with iso-propanol. Instead regular hospital spirit (70%) or alcohol swaps containing alcohol can be used.
Alectia A/S - Monday, March 10, 2008



Replacing benzine with rape oil in connection with cleaning simulation-dolls
Large amount of benzine have been used to remove glue from simulation dolls which is used in connection with educating doctors and nurses.
The glue comes from plaster, venflons and other things which are glued on the dolls.
Instead it is possible to use rape oil which is totally harmless. It takes a little more work but it is possible. When cleaning large amount of glue from the dolls petroleum is used which is still better than benzine.

Alectia A/S - Friday, March 07, 2008



Korrosionshæmmende maling til togaksler
Ved maling af aksler har DSB S-tog udskiftet en sundhedsskadelig maling med 30-50% Naphta(CAS nr. 64742-82-1 ) med MAL-kode 2-1. Man anvender nu en maling uden faremærkning med MAL-kode 00-1.
DSB S-tog a/s - Wednesday, February 27, 2008



Erstatning af syrer under bejdsning i jern - og maskinindustrien
Termisk afgratning af metalemner sker ofte med brug af stærke syrer som fosforsyre og svovlsyre. Disse kan erstattes af syrefri produkter.
Alectia A/S - Thursday, February 21, 2008



Substitution of Xylene with Tissue-Clean in connection with preparation of tissue
Xylen has for many years been used in connection with clearing of Tissue.
Instead the product Tissure-Clean can be used which is based on IsoAlkanes


Alectia A/S - Friday, March 07, 2008



Brug af Chloroform og methylenchlorid til limning af plexiglas
På Anæstesilab på Herlev Sygehus bruges Chloroform til limning af plexiglas. Chloroform er sundhedsskadelig med R40
På Medicoteknisk afd. Gentofte anvendes methylenchlorid til limning af plexiglas. Methylenchlorid er sundhedsskadelig med R40
Alectia A/S - Thursday, February 14, 2008



Brug af rapsolie til fjernelse af klistermærker
Raspolie har erstattet brugen af Rensebenzin og acetone
Kontaktperson Urologisk afd. Lene Thønnings Herlev Hospital
Alectia A/S - Tuesday, February 12, 2008



Brug af Bonneys Blue til optegning ved operation
Erstattet af tegnepenne
Kontaktperson Jytte Kronborg - Plaskirurgisk afd. V Herlev Hospital
Alectia A/S - Tuesday, February 12, 2008



Citric- and acetic acid for cleaning production equipment
Nitric acid for cleaning production equipment in sugar production was substituted with citric- and acetic acid.
Nakskov Sukkerfabrik - Thursday, February 07, 2008



Environmentally friendly diapers without acrylic acid
Abena has substituted the super-absorbing agent based on acrylic acid to an absorbent based on wheat starch and granulates. The sizing material is substituted to a mixture of resin and vegetable oil, the top band to a mixture of lycra and plastics. The paper used is bleached without use of chlorine.
Abena - Thursday, February 07, 2008



Cement med reduceret indhold af hexavalent chrom
I Danmark (og EU) er det ikke tilladt at anvende cement med et indehold af vandopløseligt chromat på mere end 2 mg pr. kg tør cement.
Reduktionen sker i praksis ved at tilsætte en opløsning af jern(III)-sulfat til cementen. Herved reduceres den vandopløselige hexavalente chrom til uopløselig trivalent chrom.
Reduktionen af hexavalent chrom i cementen har bevirket et stort fald i tilfælde af chrom-allergi i Danmark.

Alectia A/S - Thursday, February 07, 2008



Use of resin and cleaningagents in handball
A report concerning the use of resin in professionel danish handball, concludes that it is possible to use colofonium-free resin from a jar. The report also contains suggestions for emulgating cleaning agents for cleaning after the fight.
JobLiv Danmark - Tuesday, December 04, 2007



Afrensning af rammer i vaskemaskine -serigrafi
NS System A/S - Wednesday, January 10, 2007



Cleaning of tools for printing on textile
In a serigraphy production involving printing on textiles, a tool cleaning agent consisting of odourless kerosene has been replaced by a product based on vegetable oils and esters.
NS System A/S - Wednesday, January 10, 2007



Screen opener and cleaning fluid at label printing house
A large label printing house has abolished the use of a diluent containing large amounts of toluene (CAS No. 108-88-3 Toluene ) code-number 5-3. A product containing dibasic esters with code-number 1-1 is now used for automatic frame washing. As screen opener, a product with code-number 3-1 is used.
Skanem Hobro A/S - Wednesday, January 10, 2007



UV inks - serigraphy printing
In serigraphy printing on plastic film, solvent-based printing ink was formerly used. Today, UV inks are used.
Ole Nonbye a/s - Wednesday, January 10, 2007



Flame retardant without bromine
A flame retardant based on citric acid has been suggested as an alternative to brominated flame retardants on textiles, paper and decoration. The safety data sheet is available at http://www.pyrotech.dk/upload/pdf/9010%20-%209014.pdf Externt link.
Miljøkontrollen, København - Monday, December 18, 2006



Serigraphy - volatile screen opener/cleaning fluid
In serigraphy, a screen opener containing toluene, heptane, ethyl acetate (CAS No. 141-78-6 Ethyl acetate ) and isopropanol (code-number 5-3) was used. This has been replaced by a liquid with code-number 3-1, which contains benzine, acetone (CAS No. 67-64-1 Acetone ) and small amounts of isopropyl acetate and methoxy propanol, and a liquid with code-number 3-3, which contains gamma-butyrolactone and N-methylpyrrolidone.
Mekoprint A/S - Monday, December 11, 2006



Serigraphy - replacement of cleaning fluids
In serigraphy printing on glass, oil-based inks containing lead, cadmium and lithium were formerly used. As screen opener and to clean the frames, ink removers with several highly volatile components were used. Today, glass ink containing glycol ether and acetate is used. The ink can be removed with water, and a cleaning agent is therefore no longer needed. Occasionally, a frame cleaning agent containing butyldiglycol and propylene carbonate as main ingredients is used.
Scanglas A/S - Monday, November 27, 2006



Serigraphy - UV inks at small printing office
A small serigraphy printing office has replaced solvent-based inks with UV inks for most tasks.
Scandic Serigrafi - Monday, November 27, 2006



Serigrafi - rensevæske til manuel rengøring af rammer
JO Serigrafi - Monday, November 27, 2006



Solvent inks and UV inks for metal and fluorescent printing
In serigraphy printing on metal, vinyl and paper and in fluorescent printing, solvent inks were previously used. To avoid evaporation from inks and cleaning agents, UV inks are now used.
A/S BB Serigrafi & Offset - Monday, November 27, 2006



Serigrafi - rensevæsker til rengøring af skrabere og rakler
A/S BB Serigrafi & Offset - Monday, November 27, 2006



Serigraphy - degreasing of fabric in frames
In serigraphy printing on paper, cardboard, pasteboard, plastic, wood, and glass, the company now uses coated fabric, so that washing is completely avoided. Before, a soap solution was used for washing the fabric.
JobLiv Danmark as - Monday, November 27, 2006



Suction of oil in connection with change of motor oil
When changing oil on a car through the drain plug, oil was often spilled. By using an oil suction apparatus, spills and thus use of strong cleaning agents were avoided.
Solrød Kommune - Wednesday, November 01, 2006



Alternatives to chlorine-containing lubricants for demanding metal working in stainless steel and titanium
Chloroparaffins are used in considerable amounts as high-pressure additives in metal working lubricants. They are considered risky in terms of health and the environment. The example is a summary of a project aimed at mapping existing alternative non-chlorinated lubricants for demanding non-cutting metal working tasks, testing the lubricating properties of selected lubricants, and evaluating the health-related and environmental properties of the lubricants.
Danish Environmental Protection Agency - Tuesday, February 14, 2006



Environmentally sounder alternatives to PFOS compounds and PFOA
Perfluorooctanesulphonate (PFOS) and a number of related perfluorated compounds (perfluorooctane acid (PFOA)) are used in numerous industrial and consumer products. These potentially hazardous compounds give rise to increasing concern. The example is a summary of a report evaluating whether suitable less hazardous alternatives can be found.
Miljøstyrelsen - Friday, February 03, 2006



Unleaded soldering of electronics
The experiences of five large Nordic companies in connection with substitution of leaded soldering products are described. As successful substitutes, tin/silver/copper compounds are mainly used.
SINTEF - Thursday, December 15, 2005



Permanent wave lotions for hairdressers
Permanent wave lotions for permanent-waving of hair almost always contain ammonia (CAS No. 7664-41-7 Ammonia ) and mercaptoacetic acid (CAS No. 68-11-1 α-Mercaptoacetic acid ). Hairdressers experience respiratory problems and skin irritation. An environmentally certified hairdresser has found a permanent wave lotion with amino acid instead of mercaptoacetic acid and ethanolamine instead of ammonia.
JobLiv Danmark as - Friday, November 11, 2005



Cleaning of baking sheets
For thorough cleaning of baking sheets in an oven, triple ammonia (labelled "Corrosive" and "evaporating") has been replaced by soft soap (labelled "Irritant").
JobLiv Danmark as - Tuesday, October 18, 2005



Substitution af miljøskadelige stoffer i bilvaskekemikalier
DHI - Institut for Vand og Miljø - Monday, April 04, 2005



Phosphate-based flame retardants for plastic
Brominated flame retardants (suspected of being endocrine disrupters and feto-toxic) in plastic have been replaced by phosphate-based flame retardants.
JobLiv Danmark as - Thursday, January 06, 2005



Weed control without herbicides
Various alternatives to herbicides for weed control are reviewed in this example.
COWI A/S - Friday, August 06, 2004



Waterproofing of concrete cracks
For waterproofing of concrete constructions, acryl-based products can be used instead of products based on polyurethane.
COWI A/S - Friday, August 06, 2004



Biological fungicide for seeds
As an alternative to chemical fungicide-treatment of seeds, a commercial biological fungicide based on Gliocladium roseum, a very common fungus, has been developed.
COWI A/S - Thursday, August 05, 2004



CO2 as coolant in heat pumps
Greenhouse gases, e.g. HFCs (hydrofluorocarbons), have typically been used as coolant in heat pumps. Instead, heat pumps with CO2 as coolant can be used.
COWI A/S - Thursday, August 05, 2004



Alternatives to PVC and phthalates
There are many alternatives to PVC and phthalates for use in office supplies, rainwear, outdoor wear, rubber boots and waders, toys etc. The Danish Environmental Protection Agency’s fact sheets comment on alternative plasticisers in PVC, alternative plastic types and completely other materials than plastic.
COWI A/S - Thursday, August 05, 2004



Alternatives to soft PVC in the construction industry
Soft PVC is used in the construction industry. Many PVC-free alternatives for use in signal and telephone cables, flexible wires/cables, installation cables, etc., are available.
COWI A/S - Thursday, August 05, 2004



Substitution of TGIC hardener in powder finish
The substance triglycidyl isocyanurate (TGIC (cas 2451-62-9 1,3,5-Triglycidyl isocyanurate )) was used as hardener in the production of powder finish. TGIC is an allergenic and T-labelled substance. The example refers to a report comparing the environmental impacts that occur if TGIC is replaced by beta-hydroxy alkylamide. There are both advantages and disadvantages related to this substitution. Link to report with English abstract.
COWI A/S - Thursday, November 01, 2007



Reduced use of phthalates in the textile and clothes industry
In the textile and clothes industry, phthalates are used for softening PVC in connection with PVC-coated textiles, e.g. tents, tarpaulins, rainwear and work clothes. Plasticisers based on phosphate, benzoate or sulphonate can be used instead.
COWI A/S - Wednesday, August 04, 2004



Use of halogen-free fire retardants in fibre-reinforced polyethylene foils
Instead of halogen-containing fire retardants (especially brominated), it is possible to use halogen-free fire retardants in fibre-reinforced polyethylene foils.
COWI A/S - Wednesday, August 04, 2004



Substitution af HFC, PFC og SF6
COWI A/S - Wednesday, August 04, 2004



Band welder / bundling machine
Band welders use polystyrene bands that are hot welded together. Instead of hot welding, ultrasonic welding can be used.
JobLiv Danmark as - Tuesday, August 03, 2004



Replacement of biocides in bottom paint for ships with enzymes
The use of tributyltins, TBT, as anti-fouling agents for ships of less than 25 m has been forbidden in Denmark since 1991. The project collects information about many alternative biocides and examines whether proteolytic enzymes can replace the anti-fouling agents currently used in bottom paints, e.g. copper.
COWI A/S - Tuesday, August 03, 2004



Substitution of cobalt siccatives in air-drying paints
Cobalt siccatives, methyl ethyl ketoxime and hydroquinone are all chemical compounds used as additives in air-drying paints and inks. Due to their damaging effects on the environment and health, there is a general wish to reduce the use of these substances. Various alternatives to the substances concerned have been examined, as regards both their technical suitability and their effects on the environment and health, and assessed in relation to the present products.
COWI A/S - Tuesday, August 03, 2004



Constructive wood preservation
For industrial pressure-treatment of wood, impregnation products of the copper chrome arsenic type were used. An alternative method is constructive wood preservation.
COWI A/S - Tuesday, August 03, 2004



Environmentally sound sand blasting material
In the building and construction industry, sand blasting materials with quartziferous sand are used. Sand blasting products based on the inorganic part of sewage sludge have been developed. These products can replace the blasting products used hitherto.
COWI A/S - Tuesday, July 06, 2004



Fugtisolering af stålkonstruktion
COWI A/S - Tuesday, July 06, 2004



Miljørigtig projektering
COWI A/S - Monday, July 05, 2004



Vegetable mould release oil for concrete casting
Mineral mould release oils for casting moulds and machines have been replaced by vegetable oils.
COWI A/S - Monday, July 05, 2004



Grøn beton
COWI A/S - Monday, July 05, 2004



Maling indeholdende xylen
Arbejdstilsynet - Thursday, August 21, 2003



Autolakering - vandige produkter fremfor opløsningsmiddelholdige
MALER BST - Thursday, August 21, 2003



Ovnrens - svien og kløen
Arbejdsmiljøcentret - Monday, July 07, 2003



Neutralisering af vaskevand
JobLiv Danmark as - Thursday, July 03, 2003



Fra styren til epoxy
JobLiv Danmark as - Thursday, July 03, 2003



Nikkelbad - forslag til alternativer
Arbejdsmiljøcentret - Thursday, June 26, 2003



Jointing compound - from styrene to two component methacrylate
The company, which produces rollers for the printing industry, used a jointing product with 13-18% styrene. This product has now been replaced by a two component adhesive based on methacrylate and dibenzoyl.
H. Gerhardt A/S - Thursday, June 26, 2003



Metallim - fra epoxy til metacrylat
H. Gerhardt A/S - Thursday, June 26, 2003



Afrensning ved reparation og service
ABB A/S - Tuesday, June 24, 2003



Fillers, jointing compounds and stoppings
In the building and construction industry, fillers and other stoppings containing epoxy and polyurethane, solvents or other volatile components are used. Many product groups are reviewed. Epoxy products for concrete renovation, for example, are replaced by polyacrylate-based products.
Miljøstyrelsen - Monday, May 26, 2003



IPA-sprit afløst af special cleaner
Bang & Olufsen A/S - Friday, March 28, 2003



Rustbeskyttelse af metalplader
JobLiv Danmark as - Monday, March 24, 2003



Cleaning of printed circuit boards after soldering
Using freon for this purpose is prohibited in Denmark. Instead, an alkaline detergent in an industrial automatic dishwasher is used.
BST Århus - Monday, March 24, 2003



Miljøvurdering af kemikalier (scoresystem)
COWI A/S - Sunday, May 23, 2004



Reducing the use of chlorine-containing bleaching agents in the textile industry
The textile industry uses bleaching agents containing sodium chlorite, hypochlorite of soda and hydrogen peroxide together with hardly-degradable coordinate links. These can be replaced by hydrogen peroxide combined with more environmentally sound coordinate links, such as polycarboxylates, polyacrylates, hydroxy carboxyl acid or sugar copolymers.
COWI A/S - Sunday, May 23, 2004



Afrensning af silikonepuder til trykning
LEGO System A/S - Monday, March 08, 2004



Substitution af methanol til ethanol
JobLiv Danmark as - Thursday, January 29, 2004



Cleaning of cable ends
In maintenance work on the electricity supply network, the municipality formerly used benzine for cleaning off cable ends. Today, a water-based degreaser is used.
JobLiv Danmark as - Monday, November 24, 2003



Alternative alloys to replace leaded bronzes
To replace leaded bronzes at foundries, cobber-based casting alloys, e.g. tin bronze consisting of cobber, tin (CAS No. 7440-31-5 Tin ) and lead 0.8% (CAS No. 7439-92-1 Lead ), can be used.
Industriens Branchearbejdsmiljøråd - Thursday, October 16, 2003



ABC-system til vurdering af kemikalier
Brødrene Hartmann A/S - Monday, October 13, 2003



Kvældemiddel til papemballage
Brødrene Hartmann A/S - Monday, October 13, 2003



Farve på emballage
Brødrene Hartmann A/S - Monday, October 13, 2003



Vegetable cleaning agent for automatic washing on offset printing machines
In automatic washing systems on offset printing machines, rollers are cleaned with volatile cleaning agents. These can be replaced by vegetable cleaning agents.
JobLiv Danmark as - Wednesday, September 17, 2003



Trykfarver til flexotryk
SCA Packaging Grenaa - Wednesday, September 17, 2003



Afrensning af klicheér.
SCA Packaging Grenaa - Wednesday, September 17, 2003



Kemikaliesanering og registrering som grundlag for substitution
SCA Packaging Grenaa - Wednesday, September 17, 2003



Limning af bagsider af klichéer
SCA Packaging Grenaa - Wednesday, September 17, 2003



Offset printing without alcohol in the damping solution
A printing house has replaced a damping solution containing alcohol with a damping solution that does not contain alcohol.
JobLiv Danmark as - Tuesday, September 16, 2003



Cleaning of rubber blanket without using liquid
Volatile solvents are used for cleaning of rubber blankets on offset printing machines. A cleaning system using a pre-primed cleaning blanket can be used instead.
JobLiv Danmark as - Tuesday, September 16, 2003



Floor cleaning agent for dark wooden floors
At a residential nursing home, floor oil containing 65 per cent organic solvents was used for treating the floors. This has been replaced by cold-pressed linseed oil.
JobLiv Danmark as - Monday, September 15, 2003



UV-lakker og trykfarver
JobLiv Danmark as - Monday, September 15, 2003



Afvaskere til serigrafi
JobLiv Danmark as - Monday, September 15, 2003



Vegetable printing inks
The company, which works with mineral printing inks, washed rollers and rubber blankets with organic solvents. By replacing the printing inks with vegetable printing inks, the frequency of cleaning was reduced.
JobLiv Danmark as - Monday, September 15, 2003



Cleaning of screen rollers for flexo printing
A packing materials factory used organic solvents to clean screen rollers on flexo printing machines. The manual cleaning has been replaced by an alkaline cleaning bath containing sodium hydrogen carbonate (CAS No. 144-55-8 Baking soda ).
JobLiv Danmark as - Monday, September 15, 2003



PU glue for packing materials
A packing materials factory formerly laminated foils with glue containing isocyanate TDI (toluene diisocyanate). The glue has now been replaced by PU glue that contains isocyanate MDI (diphenylmethane diisocyanate).
JobLiv Danmark as - Monday, September 15, 2003



Afvaskere til offsettryk
JobLiv Danmark as - Friday, September 12, 2003



Brunering - fra giftigt/ætsende produkt til nikkelsulfat
Jern og Metalbranchens BST - Thursday, September 11, 2003



Glue based on dichloromethane replaced by dual adhesive tape
A company used glue based on dichloromethane (CAS No. 75-09-2 Dichloromethane ) to glue plastic plates on to polycarbonate plates. The glue can be replaced by dual adhesive tape.
Jern og Metalbranchens BST - Thursday, September 11, 2003



Vurdering af 3 slibemidler.
JobLiv Danmark as - Thursday, September 11, 2003



Cleaning of rollers with benzine
The company used benzine to remove talcum powder from rollers. Microfibre cloths can be used instead.
JobLiv Danmark as - Thursday, September 11, 2003



Rustbeskyttelse.
JobLiv Danmark as - Thursday, September 11, 2003



Substitution af køle-smøremiddel.
JobLiv Danmark as - Wednesday, September 10, 2003



Cleaning of colour fibre nozzles with methylethyl ketone
The company used methylethyl ketone (MEK)(CAS No. 78-93-3 2-Butanone ) and dichloromethane (CAS No. 75-09-2 Dichloromethane ) for cleaning of colour fibre nozzles. Instead, N-methyl-2-pyrrolidone (CAS No. 872-50-4 1-Methyl-2-Pyrrolidinone ) can be used.
JobLiv Danmark as - Wednesday, September 10, 2003



Epoxylim til metal.
JobLiv Danmark as - Wednesday, September 10, 2003



Methylene chloride for cleaning of nozzles in ultrasonic bath
The company used methylene chloride (CAS No. 75-09-2 Dichloromethane ) in an ultrasonic bath to remove urethane acrylate from nozzles and filters. This has been replaced by cyclohexanone (CAS No. 108-94-1 Cyclohexanone ).
JobLiv Danmark as - Tuesday, April 04, 2006



Alternative to formamide for hybridisation
A laboratory used formamide (CAS No. 75-12-7 Formamide ) for in-situ hybridisation. Instead, dipropyleneglycol (CAS No. 25265-71-8 Dipropylene glycol ) or carbamide (urea) can be used.
JobLiv Danmark as - Wednesday, September 10, 2003



Rengøringsprodukter til vaskehal for biler.
JobLiv Danmark as - Tuesday, September 09, 2003



Køle-smøremiddel med mange indholdsstoffer
JobLiv Danmark as - Tuesday, September 02, 2003



Styrene-free adhesive anchor system
In the building and construction industry, chemical adhesive anchor systems based on styrene were used for concreting steel reinforcement and threaded bars. Styrene-free products can be used. Many suppliers of adhesive anchor systems no longer sell adhesive anchor systems with styrene.
JobLiv Danmark as - Tuesday, September 02, 2003



Immunoblotting without methanol (CAS No. 67-56-1 Methanol )
A laboratory used methanol (CAS No. 67-56-1 Methanol ) when performing immunoblotting in accordance with the "Western blotting" method. This has been replaced by ethanol (CAS No. 64-17-5 Ethanol ).
JobLiv Danmark as - Tuesday, September 02, 2003



Fugtisolering af fundamente og udvendige kældervægge.
JobLiv Danmark as - Tuesday, September 02, 2003



Olieafrensning af gulv
JobLiv Danmark as - Monday, September 01, 2003



Unleaded solder wire
A company which produces metal blanks for the electronics industry used leaded solder wire. This has been replaced by unleaded solder wire.
JobLiv Danmark as - Tuesday, April 04, 2006



From pesticides to annual ground cover
Planting up all public areas with annual ground cover, e.g. crimson clover, annual lupine, tansy-leaf phacelia and seed mixtures with different meadow plants, has been initiated, and pesticides have been eliminated.
JobLiv Danmark as - Friday, August 29, 2003



Isolering med mineraluld
Arbejdstilsynet - Thursday, August 21, 2003



Spartelmasse med styren
Arbejdstilsynet - Thursday, August 21, 2003



Svejsning med thoriumlegerede elektroder
Arbejdstilsynet - Thursday, August 21, 2003



Maling af stål
Arbejdstilsynet - Thursday, August 21, 2003



Reparation and surface treatment of ships
A product containing coal tar (CAS 8007-45-2 , 84650-4-4) was substituted to a product without coal tar.
Danish Working Environmenet Authority - Wednesday, October 29, 2008



Opvaskemiddel med klor i børnehave
Arbejdstilsynet - Thursday, August 21, 2003



Isolering af højtrykskedel
Arbejdstilsynet - Thursday, August 21, 2003



Lim og spraymaling i fritidsordning
Arbejdstilsynet - Thursday, August 21, 2003



Indendørs maling
Arbejdstilsynet - Thursday, August 21, 2003



Limning af vandrør
Arbejdstilsynet - Thursday, August 21, 2003



Rensning af værktøj på bådeværft
Arbejdstilsynet - Thursday, August 21, 2003



Afrensnings af rammer, fortynding af farver, trykfarve til diverse emner
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning af metalemner med trichlorethen
Arbejdstilsynet - Thursday, August 21, 2003



Sprøjtemaling med bly til lakering af vogne
Arbejdstilsynet - Thursday, August 21, 2003



Boning af gulv med terpentinholdig voks
Arbejdstilsynet - Thursday, August 21, 2003



Træ-møbellim med formaldehyd
Arbejdstilsynet - Thursday, August 21, 2003



Opblanding af mørtel
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning af metalemner før lakering
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning med trichlorethylen
Arbejdstilsynet - Thursday, August 21, 2003



Afrensning af værktøjer til polyesterstøbning.
Arbejdstilsynet - Thursday, August 21, 2003



Rengøring af værktøjer til polyesterstøbning
Arbejdstilsynet - Thursday, August 21, 2003



TIG-svejsning med thoriumlegerede elektroder
Arbejdstilsynet - Thursday, August 21, 2003



Afrensning af valser
Arbejdstilsynet - Thursday, August 21, 2003



Lager med produkter med høje kodenumre (MAL-koder)
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning af messing med trichlorethylen
Arbejdstilsynet - Thursday, August 21, 2003



Cobolt til fremstilling af indikatorpapir
Arbejdstilsynet - Thursday, August 21, 2003



Oil in nail gun at saw mill
At a sawmill, mineral oil has been replaced by rape seed oil in a nail gun.
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning med trichlorethylen
Arbejdstilsynet - Thursday, August 21, 2003



Affedtning med trichlorethylen
Arbejdstilsynet - Thursday, August 21, 2003



Brunering - fra giftigt/ætsende til nikkelsulfat
Arbejdstilsynet - Thursday, August 21, 2003



Roof flashing without lead
Roof flashing with materials that contain lead can be replaced by a material that contains aluminium.
Poul-E Meier ApS - Wednesday, August 27, 2003



Korrosionsbeskyttelse med lavere MAL-kodenummer
Dronningborg Industries A/S - Monday, August 25, 2003



From solvent to demineralised water
Degreasers with solvents, including chlorated solvents, for washing of metal blanks were replaced by a fully automatic washing system with strong or weak alkaline degreasers or demineralised water.
Grundfos A/S - Monday, August 25, 2003



Paraffin preservation without xylene
For animal preservation, xylene (CAS No. 1330-20-7 dimethylbenzene ) or toluene (CAS No. 108-88-3 Toluene ) was used. Purified kerosene can be used instead.
Zoologisk Museum - Monday, August 25, 2003



Carcinogenic substance for analysis of fatty acid
At a university, the students used chloroform (CAS No. 67-66-3 Chloroform ) to determine free fatty acid in oil. A method based on ethanol (CAS No. 64-17-5 Ethanol ) can replace the use of chloroform.
Biocentrum, DTU - Friday, August 22, 2003



Cleaning of stainless blanks by means of hydrofluoric acid
After TIC welding, a workshop cleaned the metal blanks with hydrofluoric acid. The use of a machine with phosphoric acid has replaced the hydrofluoric acid.
Biocentrum, Technical University of Denmark - Tuesday, April 04, 2006



Produktvalg til industriel overfladebehandling
MALER BST - Thursday, August 21, 2003



Pregnant housepainters and chemical products
Several examples describe the assessment of pregnant women's use of paint products.
MALER BST - Thursday, August 21, 2003



Maling af bro - samme korrosionsbeskyttelse med vandigt produkt
MALER BST - Thursday, August 21, 2003



Maling af galvaniserede elmaster
MALER BST - Thursday, August 21, 2003



Maling af stålbro med vandige produkter
MALER BST - Thursday, August 21, 2003



Rengøring af rørepinde med silikone
Arbejdsmiljøcentret - Monday, July 07, 2003



Removal of surplus colour with IPA spirit
To remove surplus colour when manufacturing number plates, the company used IPA spirit with ethanol 90% (CAS No. 64-17-5 Ethanol ) and 2-propanol 10%. The development of a tool consisting of a hollow handle with a cotton core reduced the risk of skin contact consi
Kayser Plast - Monday, July 07, 2003



Afvaskemiddel til farvekasser
Dagbladet Ringsted - Monday, July 07, 2003



Rammevask til serigrafi
JobLiv Danmark as - Thursday, July 03, 2003



Colour paste without phthalates for acrylics
Many of the colour pastes used for colouring acrylics in the plastics industry are based on dibutyl phthalate. Colour paste based on citric acid ester is now available.
Repsol Brønderslev A/S - Wednesday, July 02, 2003



Cleaning after polymerisation of acrylate plastic
For cleaning of mixing tubes after polymerisation of acrylate plastic, the company used methylene chloride (CAS No. 75-09-2 Dichloromethane ). A process in which the mixing tubes are cleaned with hot water (90° C) in a high-pressure washing system has now been introduced.
Repsol Brønderslev A/S - Tuesday, April 04, 2006



Surface-active substances for leak testing of plastic welds
For leak testing welds in plastic tubs, the company used a product that caused skin problems. The product has been replaced by ordinary sulphone.
BST Sjælland - Tuesday, July 01, 2003



Afvaskemiddel til trykvalser
Dagbladet Politiken - Thursday, June 26, 2003



Opsamling af oliespild
Løgstør Rør A/S - Friday, June 20, 2003



Water-based degreasing of aluminium
Many companies use solvent-based agents, primarily trichloroethylene, for degreasing metal. Water-based agents can be used for degreasing steel, aluminium and several other metals.
Miljøstyrelsen - Monday, May 26, 2003



Ukrudtsbekæmpelse på belægninger
Skov & Landskab (FSL) - Monday, May 26, 2003



Afrensning af metaldele
AH Værktøj- og metalvarefabrik A/S - Monday, May 12, 2003



Klæber til gummi og metal
Ellegaard Conveyor - Monday, May 05, 2003



Afrensning af trykfarver
Superfos Packaging - Friday, April 25, 2003



Chrom/nikkelallergi ved slibning i rustfrit stål
Lars Østergaard ApS - Wednesday, April 09, 2003



IPA-sprit erstattet af vandbaseret affedtningsmiddel
BST Århus - Tuesday, March 25, 2003



Epoxy primer replaced by polyvinyl butyral primer
For priming of steel blanks in a system, a company used a dual component epoxy primer. The epoxy primer has been replaced by a dual component polyvinyl butyral primer (PVB primer).
BST Århus - Tuesday, March 25, 2003



Microfibre cloths for cleaning of metal surfaces
The company used cleaning agents containing solvents for cleaning electronic equipment cabinets. The cleaning agent has been replaced by microfibre cloths with clean water or mild detergent.
JobLiv Danmark as - Monday, March 24, 2003



Replacement of lead in alloy
For plastic moulding, a company is using an alloy containing lead. Testing a mixture of bismuth and tin instead of lead is suggested.
BST Sjælland - Monday, March 24, 2003



Removal of acrylate residue without using dichloromethane
Metal nozzles used for coating optical fibres are cleaned from acrylate residues in an ultrasonic bath filled with dibasic esters; thereafter continued operation of the tools. Originally dichloromethane was used, then N-methylpyrrolidone was tested, and finally DBE (dibasic esters) were adopted.
JobLiv Danmark as - Monday, March 24, 2003



Afrensning af silketrykskabeloner
Bang & Olufsen A/S - Monday, March 24, 2003



Painting of lines on car decks
A shipping company used solvent-based paint that contained lead chromate (CAS No. 7758-97-6 Lead Chromate ) to paint lines on car decks. This paint has been replaced by water-based paint.
Søfartens Arbejdsmiljøråd - Monday, March 24, 2003



Replacement of chlorine
Chlorine was used for cleaning of dairy test tubes (milk test tubes). Now, rodalon water (benzalkonium chloride) is used instead.
BST Svendborg - Monday, March 24, 2003



Afrensning af bremser
DTC - Monday, March 24, 2003



Cleaning of engine parts
Large amounts of solvents were formerly used for cleaning of engine parts. An alkaline heavy-duty cleaner with code-number 00-1 when diluted is now used instead.
Forsvarets BST - Monday, March 24, 2003



Boiler water systems without hydrazine as oxygen absorbent
Hydrazine, which is carcinogenic, is used as oxygen absorbent in boiler water to avoid corrosion. There are many alternative products that do not contain hydrazine.
DTC - Monday, March 24, 2003



Rengøring af sygehusinstrumenter
BST Midtjylland - Monday, March 24, 2003



Methylene chloride for cleaning of plastic before gluing
For degreasing before gluing or welding, the company formerly used methylene chloride (CAS No. 75-09-2 Dichloromethane ). On polypropylene (PP) and PVC surfaces methylene chloride has been replaced by ethanol (CAS No. 64-17-5 Ethanol ).
Instrumatic A/S - Monday, March 24, 2003



Stabiliser for PVC
In the plastics industry, leaded stabilisers were earlier used in connection with the production of hard PVC blanks. Stabiliser systems based on calcium and zinc compounds can replace lead.
BST Århus - Monday, March 24, 2003



Washing of windows with microfibre cloths
A restaurant used to use a glass cleaning product containing organic solvents for cleaning windows. Today, microfibre cloths are used.
BST Århus - Monday, March 24, 2003



Plasticisers in PVC carpets
A company used phthalate plasticisers with DEHP for the production of PVC-backed carpet tiles. DEPH has now been replaced by DINP.
BST Århus - Monday, March 24, 2003



Fixing of end plugs - from glue to mechanical joining
An iron and metal company used to fix end pieces on tap fittings by means of cyanoacrylate-based glue. The design of the end pieces was changed so that the joining no longer requires gluing, but only mechanical joining.
BST Århus - Monday, March 24, 2003



Substitution of cellulose diluent for cleaning of conveyor belt
Cellulose diluent was used in order to remove residual glue from a conveyor belt. The company now uses methylated spirit instead of cellulose diluent.
BST Lolland-Falster - Monday, March 24, 2003



Acrylate-based surface coating for cardboard
A printing house used UV-hardening acrylate-based surface coatings for the finishing of cardboard. Now, water-based coating is used instead.
JobLiv Danmark as - Monday, March 24, 2003



Cleaning of wells before renovation
In connection with the renovation of wells, the well walls were formerly cleaned using solvent-containing caustic products and products containing fat-dissolving tensides, cultures of bacteria and solvents. Instead, the company now uses a degreasing detergent.
BST Århus - Monday, March 24, 2003



Vulcanisation of remould tyres without the use of a release agent
A company manufacturing remould tyres used a release agent that contained graphite and mica dissolved in heptane in a mould when performing the vulcanisation. By unpacking the tyres immediately after the vulcanisation while they are still hot, the company
BST Århus - Monday, March 24, 2003



Degreasing of rubber before repair/patching
A company in the rubber and plastics industry used to use a degreaser based on chlorated solvents to degrease rubber before repair/patching. This product has now been replaced by a cleaning agent based on citrus oil.
BST Århus - Monday, March 24, 2003



Renovation of sewage system with isocyanate product instead of epoxy product
Epoxy products were formerly used in no-dig renovation of defective sewers. By using isocyanate products with lower code-numbers, quicker hardening and reduced risk of allergy are achieved.
BST Århus - Wednesday, March 19, 2003



Lock spray with hexane and volatile solvents
A company used a lubricant containing the volatile hydrocarbon compounds 1,2-dichlorobenzene (95-50-1 1,2-Dichlorobenzene ) and n-hexane (CAS No. 110-54-3 Hexane ) as a lock spray. An alternative lock spray contains less volatile hydrocarbon mixtures and very small amounts of glycolether and isobutanol.
BST Århus - Wednesday, March 19, 2003



Cleaning agent for removal of polyester residue
A company used the carcinogenic substance dichloromethane (CAS No. 75-09-2 Dichloromethane ) in order to remove polyester residue from mixing chambers. Dichloromethane has been replaced by N-methyl-2-pyrrolidone (CAS No. 872-50-4 1-Methyl-2-Pyrrolidinone ), which must, however, be heated to 60° C and circulated in the chamber for a somewhat longer time.
BST Århus - Monday, March 17, 2003



Replacement of PVC glue by mechanical joining
A company in the rubber and plastics industry used to glue plastic blanks together by means of tetrahydrofuran-containing PVC glue. The company has replaced gluing with mechanical joining methods, e.g. snap joining.
BST Århus - Monday, March 17, 2003



Substitution af sprit med kulbrinteblanding
Arbejdsmiljø København - Tuesday, March 11, 2003



Replacement of trichloroethylene for degreasing of metal
An iron and metal company used trichloroethylene when degreasing metal parts. After a discussion of purity requirements, many of the parts are now cleaned in a closed washing system using alkaline cleaning fluid.
Autobranchens BST - Tuesday, March 11, 2003



Benzine for removal of adhesive from wood
A furniture manufacturer formerly used benzine for removing adhesive residue in the production process. Today, abrasive cream cleaners are used instead.
BST Sjælland - Monday, March 10, 2003



Paraffinolie som immersionsolie
LAB-Link - Thursday, March 06, 2003



Silicagel - blå eller orange
LAB-Link - Thursday, March 06, 2003



Substitution of xylene in clearing agent for tissue specimens
In hospital laboratories, a series of experiments led to the ester butyldecanoate being used instead of xylene as clearing agent for tissue specimens.
LAB-Link - Wednesday, March 05, 2003



Extraction without using organic solvents
Solid phase micro extraction can replace the use of organic solvents in many extractions at analysis laboratories. The Faculty of Agricultural Sciences has implemented this substitution for types of sample that differ as widely as, e.g., livestock manure and food.
LAB-Link - Wednesday, March 05, 2003



Bronopol til mælkekonservering
LAB-Link - Wednesday, March 05, 2003



Beta mercaptoethanol or DTE in protein gels?
Beta mercaptoethanol (T) liquid can be replaced in protein gels by dithioerythritol (DTE) powder (Xn). In this example, the advantages and disadvantages of this are discussed. DTE is favoured under the right production conditions.
LAB-Link - Wednesday, March 05, 2003



Konservering af prøver uden formalin?
LAB-Link - Wednesday, March 05, 2003



Abolition of chloroform, hexane and benzene in fatty acid analysis
At a laboratory, chloroform (CAS No. 67-66-3 Chloroform ), hexane (CAS No. 110-54-3 Hexane ) and benzene (CAS No. 71-43-2 Benzene ) was used when analysing the fatty acid content of feeding stuffs. Hexane and benzene have been replaced by the far less harmful heptane, and chloroform by tetrahydrofuran and n-heptane.
LAB-Link - Wednesday, March 05, 2003



Preservation of animals using ethanol (CAS No. 64-17-5 Ethanol )
For many years, formalin was used when preserving animals at the University of Copenhagen. Formalin is carcinogenic and allergenic. Today, ethanol is used.
Zoologisk Museum - Thursday, November 08, 2007



Cleaning of machines and machine parts by means of vegetable fatty acids
For cleaning of machines and machine parts, organic solvents, e.g. spirit, acetone (CAS No. 67-64-1 Acetone ) and white spirit, can be replaced by products based on vegetable fatty acids.
BST Sjælland - Wednesday, March 05, 2003



Cleaning of cylinders and worms on injection moulding machines
A large plastics company used cleaning agents containing methylmetha acrylate for cleaning cylinders and worms on injection moulding machines. Today, a plastic granulate of SAN and PEHD is used instead.
LEGO System A/S - Wednesday, March 05, 2003



Substitution of lead stabilisers
The rubber and plastics industry's use of lead as stabiliser in certain plastic products can be replaced by stabilisers based on calcium zinc.
BST Sjælland - Tuesday, March 04, 2003



Dehydrering ved lufttørring i stedet for alkohol
Patologisk Institut, Hjørring Sygehus - Friday, February 28, 2003



Kviksølv ved kvantitativ proteinbestemmelse
Novo Nordisk - Friday, February 28, 2003



Ammoniakbestemmelse i kedelvand
Enstedværket, Elsam A/S - Friday, February 28, 2003



Fra propanol til ethanol (cas 64-17-5 Ethanol ) ved bestemmelse af svovlindhold i kul
Enstedværket, Elsam A/S - Friday, February 28, 2003



From methanol (CAS No. 67-56-1 Methanol ) to ethanol (CAS No. 64-17-5 Ethanol ) for determination of hydrazine in boiler water
For the determination of hydrazine in boiler water, methanol (CAS No. 67-56-1 Methanol ) was formerly used. After substitution, ethanol 96% (CAS No. 64-17-5 Ethanol ) is used in the same method.
Enstedværket, Elsam A/S - Friday, February 28, 2003



Mindre kemikalieforbrug ved jernbestemmelse i kølefødevand
Enstedværket, Elsam A/S - Friday, February 28, 2003



Vandbestemmelse i smøreolier.
Enstedværket, Elsam A/S - Friday, February 28, 2003



Cleaning of refractometer
Petrol was used for refractometer cleaning. Instead, clean water and methylated spirit are now used.
Alfa/Solo - Friday, February 28, 2003



Determination of alkali content in oil
When determining the alkali content in oil, trichloroethylene (CAS No. 79-01-6 Trichloroethylene ) and pure ethanol 1:1 (heated) were formerly used. The laboratory changed over to heated methylated spirit (ethanol).
Alfa/Solo - Friday, February 28, 2003



Brominated flame retardants for plastic
In the production of certain plastic blanks, flame retardants are added to the raw material in order to improve its fire safety properties. The brominated flame retardants can be replaced by products based on triphenyl phosphate.
BST Sjælland - Thursday, February 27, 2003



Rengøring af blanke flader
LEGO System A/S - Thursday, February 27, 2003



Afrensning af maskiner og maskindele
LEGO System A/S - Thursday, February 27, 2003



Afrensning af urenheder på formværktøj
LEGO System A/S - Thursday, February 27, 2003



Afrensning af tampontrykpuder
LEGO System A/S - Thursday, February 27, 2003



Afrensning af formdele
LEGO System A/S - Thursday, February 27, 2003



Corrosion protection of moulds
For corrosion protection of moulds, a product containing approximately 70% turpentine was used. Today, a product with mineral oil and lubricant additives is used instead.
LEGO System A/S - Thursday, February 27, 2003



Cleaning of printing blocks
A large company cleaned its printing blocks using ultrasound and methylene chloride (CAS No. 75-09-2 Dichloromethane ), which is skin permeating and carcinogenic. Instead, the company now uses ultrasound and methyl butyl ketone (CAS No. 591-78-6 2-Hexanone ).
LEGO System A/S - Thursday, February 27, 2003



Opvarmning med silikoneoliebade til syntesearbejde
LAB-Link - Wednesday, February 26, 2003



Bonding of ABS plastic
For bonding of ABS plastic, a liquid based on methyl ethyl ketone (CAS No. 78-93-3 2-Butanone ) was used. The liquid has been replaced by gamma-butyrolactone (CAS No. 96-48-0 γ-Butyrolactone ) to which a small amount of plastic material has been added.
LEGO System A/S - Wednesday, February 26, 2003



Rensning af mixerhoveder
Løgstør Rør A/S - Tuesday, February 25, 2003



Tørring v.h.a. tørreperler
Løgstør Rør A/S - Tuesday, February 25, 2003



Anticorrosive agent for steel tubes
To protect steel tube ends against corrosion, an oil-containing agent was used. This agent has been replaced by a coating of foamed polyethylene (PE).
Løgstør Rør A/S - Tuesday, February 25, 2003



Slipmiddel
Løgstør Rør A/S - Tuesday, February 25, 2003



Grafiske afvaskemidler
BST Sjælland - Monday, February 24, 2003



Sur affedtning af aluminium
Miljøstyrelsen - Sunday, February 23, 2003



Rengøring af mekanisk højglanspolerede aluminiumsoverflader
Miljøstyrelsen - Sunday, February 23, 2003



Alkaline degreasing of aluminium and steel before powder finishing
Degreasing of steel and aluminium parts with trichloroethylene (CAS No. 79-01-6 Trichloroethylene ) has been replaced by degreasing with alkaline degreasers containing phosphates and tensides.
Miljøstyrelsen - Sunday, February 23, 2003



Alkaline degreasing of aluminium before electrophoresis finishing
In a large company, the use of solvents for degreasing of cast aluminium pump cases has been replaced by a combination of shot blasting of the blanks with steel balls, subsequent use of water-based cooling lubricant, washing with water at 60 degrees and degreasing using an alkaline degreasing agent.
Miljøstyrelsen - Sunday, February 23, 2003



Chloroform in analysis laboratories
A laboratory has replaced chloroform (CAS No.67-66-3 Chloroform Chloroform), which is considered carcinogenic, with N-butyl-acetate (CAS No. 123-86-4 Butyl acetate Butylacetate) as extraction solvent when analysing biological samples.
Department of Technology and Social Science, DTU - Sunday, February 23, 2003



Trykfarve uden opløsningsmidler
BST Århus - Friday, February 21, 2003



Cleaning of machines and machine parts
For removal of oil-residue from machines and machine parts, kerosene can be replaced by products based on alcohol ethoxylate and non-ionic tensides.
Plastmo A/S - Thursday, February 20, 2003



Cyclopentane foaming of hard polyurethane plastic
For foaming of hard polyurethane plastic, a foaming agent consisting of CFC, HCFC and HFC was used. In a new process, these substances can be replaced by cyclopentane.
BST Sjælland - Thursday, February 20, 2003



Carbon dioxide foaming of soft polyurethane plastic
For foaming of soft polyurethane plastic, a foaming agent consisting of CFC, HCFC or HFC was used. In a new process, HFC has been replaced by carbon dioxide (C02).
BST Sjælland - Thursday, February 20, 2003



Polyesterstøbning, miljøpolyester
BST Sjælland - Thursday, February 20, 2003



Cleaning using dibasic esters after polyester casting
Acetone (CAS No. 67-64-1 Acetone ) has been replaced by dibasic esters for cleaning tools and moulds for polyester casting.
BST Sjælland - Thursday, February 20, 2003



Gravér farve
BST Sjælland - Thursday, February 20, 2003



Kølesmøremiddel
BST Sjælland - Friday, February 07, 2003



Fortynder til serigrafifarve
BST Sjælland - Friday, February 07, 2003



Metallim
AMBU A/S - Wednesday, February 05, 2003



Lubricant used when mounting rubber parts
Ethanol as friction-reducing agent replaced by water and sulphone.
AMBU A/S - Wednesday, February 05, 2003



Udskiftning af kølesmøremiddel
AMBU A/S - Wednesday, February 05, 2003



Overfladebehandling af beton med silikone
BST Sjælland - Monday, January 27, 2003



Blyfri loddetin
Brüel & Kjær - Friday, January 24, 2003



Polermiddel til metalemner
Brüel & Kjær - Friday, January 24, 2003



Electro-chemical cleaning of metal parts
Sulphuric acid 96% replaced by nitric acid 5% in electrolytic degreasing.
Brüel & Kjær - Friday, January 24, 2003



Removal of cutting oil from metal parts
Cutting oil on bought-in metal parts was removed by electro-chemical cleaning, first with strong base and then with strong acid. This method has been replaced by cleaning in n-propylbromide in a closed system, supplemented by demands on sub-supplier.
Brüel & Kjær - Friday, January 24, 2003



Spirit-washing of metal parts in cleanroom
Metal parts with very high requirements as regards cleanliness are washed in ethanol. Plasma cleaning is tested as an alternative.
Brüel & Kjær - Friday, January 24, 2003



Removal of flux with vegetable oil and soap
Brüel & Kjær earlier used freon for removing flux residue from metal parts. Now, the parts are soaked in vegetable oil and then washed with mild detergent in an industrial automatic dishwasher. This substitution ensures a more efficient cleaning than with freon.
Brüel & Kjær - Thursday, November 01, 2007



Udskiftning af skærevæske
BST Sjælland - Thursday, January 23, 2003



Damping solution with IPA spirit used in offset printing
In offset printing, a damping solution containing isopropanol and bronopol (formaldehyde releaser) as preservative has been replaced by a damping solution containing ethanol and isothiazoline (kathone) as preservative.
BST Sjælland - Thursday, December 05, 2002



Glue for polyamide
Glue containing methanol (CAS No. 67-56-1 Methanol ) for conveyor belt. Instead, ethanol (CAS No. 64-17-5 Ethanol ) or a mixture of ethanol (CAS No. 64-17-5 Ethanol ) and gamma-butyrolactone is suggested.
BST Sjælland - Thursday, December 05, 2002



Polyurethanfjerner
BST Sjælland - Saturday, January 01, 2000



Cleaning of small metal parts using alkaline soap product
A small metal company used to remove oil and dirt from metal parts by means of trichloroethylene (CAS No. 79-01-6 Trichloroethylene ), which is considered to be carcinogenic. Instead, it has now invested in an ultrasonic bath with an alkaline soap solution.
BST Sjælland - Thursday, December 05, 2002



Erstatning af kølesmøremiddel
BST Sjælland - Thursday, December 05, 2002



Udskiftning af acetone med Enviro Poly-clean 2
BST Sjælland - Thursday, December 05, 2002



Anticorrosive paint. From solvent to water
Road grates were formerly immerse-painted in paint containing xylene (CAS No. 1330-20-7 dimethylbenzene ) having code-number 2-1, diluted with xylene-containing diluent having code-number 5-3. Water-based paint with code-number 00-1 is now used instead.
BST Sjælland - Thursday, December 05, 2002